When it comes to casino games with the highest winning chances, blackjack, baccarat, and certain variations of video poker stand out. Blackjack offers players the best odds, especially when employing basic strategy, with a house edge as low as 0.5%. Baccarat is another favorable option, boasting a low house edge on banker bets. Video poker, particularly Jacks or Better, can provide high returns with optimal play, often exceeding 99% payout rates. Choosing these games can enhance your chances of winning while enjoying the thrill of the casino experience.